Fireworks light up more than just the skies across America every Fourth of July. They spark a sense of nostalgia and tradition like few things can, igniting our American pride.
There is, after all, a lot more to fireworks than what we see.
Chemistry professor Kate Mullaugh uses a flame atomic spectrometer to demonstrate how different elements used in fireworks create different colors. (Photos by Heather Moran)
โNot too many people think about the chemistry behind fireworks, but thatโs whatโs responsible for all the beautiful colors we enjoy every Fourth of July,โ says Kate Mullaugh, assistant professor in the College of Charleston Department of Chemistry and Biochemistry. โIt all comes down to which element is being used.โ
Lithium, for example, lights up a bright pink; iron, a tangerine orange; barium, an electric green; potassium, a soft purple; and sodium, a golden yellow. But how?
โHeat excites the electrons in the atom to higher energy levels,โ says Mullaugh, explaining that the higher the heat is, the higher the energy level. โHowever, the lowest energy โgroundโ level is preferred, so, upon excitement in the hot flame, atoms will quickly relax back down. But, in doing so, they have to rid themselves of the energy somehow, and they do so by emitting the energy in the form of light.โ
If you think of the energy levels as rungs on a ladder, she says, the spaces between the rungs would be where energy is released. So, it is between those โrungsโ that we get wavelengths of light.
โThere is a relationship between the energy of light and its color,โ says Mullaugh, noting that the amount of energy released is different for each element, which causes different wavelengths of light. โSo, elements with big spacing between the energy levels will emit shorter wavelengths of light (which tend to be bluish or purple), and smaller spacing results in longer wavelengths of light (which tend to be orange or red). The color is the elementโs fingerprint.โ
To demonstrate this phenomenon, Mullaugh feeds various elements into a flame atomic spectrometer in her lab on the second floor of the School of Sciences and Mathematics Building.
Potassium creates a purple color, while lithium creates a bright pink color.
With each element she feeds into the instrument, its flame burns a different color. For example, strontium, magnesium and copper โ all commonly used in fireworks โ create a respective red, white and blue.
โBlue is the hardest to achieve because it requires a high combustion temperature, so the explosion of the firework has to be really, really hot,โ says Mullaugh, who often uses the flame spectrometer with her students in the Fundamentals Analytical Chemistry lab to measure strontium in seawater samples from the South Carolina Aquarium. โStrontium is an essential nutrient for many marine organisms, but is present in much lower concentrations than other things in seawater. So, we can use the strontiumโs specific โcolorโ to measure its concentration without interference from other elements in seawater.”
Even to Mullaugh, the colors these elements produce โ and the scientific use this occurrence can have โ is awe inspiring.
โIt is pretty cool that the same phenomenon for creating colors for our pleasure has distinct use in the lab as well,โ continues Mullaugh. โFireworks are a great example of how science and art intersect โ and how science brings beauty into our lives.โ
Indeed, whether youโre looking at our shining seas or our spacious skies, itโs the chemistry thatโs dazzling.
